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Chromyl chloride

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What is the Chromyl chloride ?

Chromyl chloride is , while it's Molecular Formula is Cl2Cr O2. Catalyst for polymerization of olefins; oxidation of hydrocarbons; in the Etard reaction for production of aldehydes and ketones; in the preparation of various coordination complexes of Cr.

What is the CAS number for Chromyl chloride ?

The CAS number of Chromyl chloride is 14977-61-8.

More information of Chromyl chloride 14977-61-8 are:

Synonyms

Chromium,dichlorodioxo- (8CI);Chromyl chloride (6CI);Chromium chloride oxide(CrCl2O2);Chromium chloride oxide (CrO2Cl2);Chromium dichloride dioxide;Chromium dioxide dichloride;Chromium oxide chloride (CrO2Cl2);Chromiumoxychloride (CrCl2O2);Chromium oxychloride (CrO2Cl2);Chromium(VI)dioxychloride;Chromyl chloride (CrCl2O2);Chromyl chloride (CrO2Cl2);Chromyldichloride;Dichlorodioxochromium;

CAS?Number

14977-61-8

Molecular Formula

Cl2Cr O2

Molecular Weight

154.901

Density

1.911 g/mL at 25 °C(lit.)

Melting Point

-96.5 °C

Boiling Point

117 °C(lit.)

Flash Point

117°C

HS CODE

2914700090

PSA

34.14000

LogP

1.14140

What is Chromyl chloride (14977-61-8) used for?

Chromyl chloride, also known as chromium(VI) oxide dichloride, is a dark red covalent liquid with a musty, burning odor. It is a highly reactive compound that is corrosive to tissue and is prepared either by distilling a dry mixture of potassium dichromate and sodium chloride with concentrated sulfuric acid or by the action of concentrated sulfuric acid on chromium(VI) oxide dissolved in concentrated hydrochloric acid. Chromyl chloride is hydrolyzed by water and reacts with solutions of alkalis to produce chromate ions. It is used as an oxidizing agent in organic chemistry and is known for its ability to oxidize methyl groups at the ends of aromatic side chains to aldehyde groupings (étard’s reaction).

InChI:InChI=1/2ClH.2Cr.5O/h2*1H;;;;;;;/q;;2*+1;;;;;/p-2/rCl2Cr2O5/c1-3(5,6)9-4(2,7)8

Articles related to Chromyl chloride:

Article

Source

Oxidation Kinetics of Chromium(III) Chloride

Sole, Kathryn C.,Moolman, Michael B.,Brown, Michael E.

, p. 525 - 530 (2007/10/02)

Characterisation of Chromium(VI) Oxide Tetrafluoride, CrOF4, and Caesium Pentafluoro-oxochromate(VI) Cs

Hope, Eric G.,Jones, Peter J.,Levason, William,Ogden, J. Steven,Tajik, Mahmoud,Turff, Jeremy W.

, p. 529 - 534 (2007/10/02)

How to get the best price on Chromyl chloride?

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